MCQ Questions Chapter 3 Electrochemistry Class 12 Chemistry

MCQ Class 12

Please refer to MCQ Questions Chapter 3 Electrochemistry Class 12 Chemistry with answers provided below. These multiple-choice questions have been developed based on the latest NCERT book for class 12 Chemistry issued for the current academic year. We have provided MCQ Questions for Class 12 Chemistry for all chapters on our website. Students should learn the objective based questions for Chapter 3 Electrochemistry in Class 12 Chemistry provided below to get more marks in exams.

Chapter 3 Electrochemistry MCQ Questions

Please refer to the following Chapter 3 Electrochemistry MCQ Questions Class 12 Chemistry with solutions for all important topics in the chapter.

MCQ Questions Answers for Chapter 3 Electrochemistry Class 12 Chemistry

Question. The standard reduction potential values of the three metallic cations X,Y and Z are 0.52, −3.03 and −1.18 V respectively. The order of reducing power of the corresponding metals is
(a) Y > Z > X
(b) X > Y > Z
(c) Z > Y > X   
(d) Z > X > Y         

Answer

A

Question. Given, E° Cl /Cl− = 1.36 V;E ° Cr3+ = −  /Cr 0.74 V
         E° Cr2O27/Cr3+ =1.33 V;E ° MnO4- /Mn2+ = 1.51V
Among the following, the strongest reducing agent is
(a) Cr
(b) Mn2+
(c) Cr3+
(d) Cl−             

Answer

A

Question. Conductance (unit Siemen’s) is directly proportional to area of the vessel and the concentration of the solution in it and is inversely proportional to the length of the vessel, then the unit of constant of proportionality is
(a) S m mol–1
(b) S m2 mol –1
(c) S–2 m2 mol  
(d) S2 m2 mol–2           

Answer

B

Question. Resistance of 0.2 M solution of an electrolyte is 50 W. The specific conductance of the solution is 1.3 S m−1. If resistance of the 0.4 M solution of the same electrolyte is 260 , its molar conductivity is 
(a) 6250 Sm2 mol−1
(b) 6.25 × 10−4 Sm2 mol−1
(c) 625 × 10−4 Sm2 mol−1
(d) 62.5 Scm2 mol−1         

Answer

B

Question. A solution of copper sulphate (CuSO4 ) is electrolysed for 10 min with a current of 1.5 A. The mass of copper deposited at the cathode (Atomic mass of Cu = 63u ) is 
(a) 0.3892 g
(b) 0.2938 g
(c) 0.2398 g
(d) 0.3928 g               

Answer

B

Question. Resistance of 0.2 M solution of an electrolyte is 50 W. The specific conductance of the solution of 0.5 M solution of same electrolyte is 1.4 Sm−1 and resistance of same solution of the same electrolyte is 280 .The molar conductivity of 0.5Msolution of the electrolyte in Sm2 mol−1 is
(a) 5 × 10−4
(b) 5 × 10−3
(c) 5 × 103
(d) 5 × 102         

Answer

A

Question. The equivalent conductance of NaCl at concentration (C) and at infinite dilution are λC and λ,respectively. The correct relationship betweenλC and λ is given as (Where, the constant B is positive) 
(a) λC = λ + (B)C
(b) λC = λ − (B)C
(c) λC = λ − (B)√C
(d) λC = λ + (B)√C         

Answer

C

Question. X g of silver is plated out on a serving tray by electrolysis of a solution containing silver in +1 oxidation state for a period of 8.0 h at a current of 8.46 A. What is the area of the tray if the thickness of silver plating is 0.00254 cm?
[Given, density of silver = 10.5 g cm−3]
(a) 10.7 × 104 cm2
(b) 1.02 × 104 cm2
(c) 4.1 × 103 cm2
(d) 10.2 × 104 cm2           

Answer

B

Question. A current of 2 A is passed for 5 h through a molten tin salt to deposit 22.2 g tin. What is the oxidation state of tin in salt ? [At. wt. of Sn =118.69 g]
(a) +2
(b) +5
(c) +3
(d) +4             

Answer

A

Question. For the reaction,
    Zn(s) + Cu2+ (0.1 M) → Zn2+ (1M) + Cu(s)
taking place in a cell, E°cell o is 1.10 V. E°cell for the cell will be{2.303 RT/F =0.0591}
(a) 1.80 V
(b) 1.07 V
(c) 0.82 V
(d) 2.14 V                     

Answer

B

Question. Given, E°Cr3+/Cr = −0.72 V; E° Fe2+/Fe 0.42 V o = −
The potential for the cell
       Cr|Cr3+ (0.1M)||Fe2+ (0.01M) |Fe is
(a) − 0.339 V
(b) − 0.26 V
(c) 0.26 V
(d) 0.339 V         

Answer

C

Question. In the electrolytic cell, flow of electrons is from
(a) cathode to anode in solution
(b) cathode to anode through external supply
(c) cathode to anode through internal supply
(d) anode to cathode through internal supply             

Answer

D

Question. When the sample of copper with the zinc impurity is to be purified by electrolysis, the appropriate electrodes are
      Cathode             Anode
(a) pure zinc         pure copper
(b) impure zinc     pure copper
(c) impure zinc     impure sample
(d) pure copper    impure sample               

Answer

D

Question. The value of the reaction quotient, Q for the cell Zn (s)| Zn2+(0.01M)| | Ag+ (1.25 M)| Ag(s) is
(a) 156
(b) 125
(c) 1.25 × 10–2
(d) 6.4 × 10–3           

Answer

D

Question. The reduction potential of hydrogen half-cell will be negative if 
(a) p (H2 ) = 1 atm and|H+| = 2.0 M
(b) p (H2 ) = 1 atm and|H+| = 1.0 M
(c) p (H2 ) = 1 atm and|H+| = 1.0 M
(d) p (H2 ) = 1 atm and|H+| = 2.0 M           

Answer

C

Question. The standard reduction potential for Fe Fe2+ / and Sn Sn2+ / electrodes are – 0.44 and – 0.14 V respectively. For the cell reaction; Fe2+ + Sn → Fe + Sn2+ , the standard emf is
(a) +0.30 V
(b) – 0.58 V
(c) +0.58 V
(d) – 0.30 V         

Answer

D

Question. How many Faraday’s are required to reduce 1 mole of BrO3 to Br –?
(a) 3
(b) 5
(c) 6
(d) 4               

Answer

C

Question. Two Faraday of electricity is passed through a solution of CuSO4.The mass of copper deposited at the cathode is (atomic mass Cu = 63.5u) 
(a) 0 g
(b) 63.5 g
(c) 2 g
(d) 127 g             

Answer

B

Question. What will be the emf for the given cell?
     Pt | H2(p1) | H+ (aq) | H2(p2 ) | Pt
(a) RT/F ln p1/p2
(b) RT/2F ln p1/p2
(c) RT/2F ln p2/p1
(d) None of these             

Answer

C

Question. The metal that cannot be obtained by electrolysis of an aqueous solution of its salts is 
(a) Ag
(b) Ca
(c) Cu
(d) Cr       

Answer

B

Question. Given, E° Cr3+ /Cr = −0.74 V;E° MnO4- /Mn2+ = 1.51V
         E° Cr2O2-/Cr3+ =1.33 V;E ° Cl /Cl−=1.33 V
Based on the data given above, strongest oxidising agent will be 
(a) Cr3+
(b) Mn2+
(c) MnO4
(d) Cl−                     

Answer

C

Question. Electrode potentials (E °) are given below :
        Cu+ / Cu = + 0.52 V, Fe3+/Fe2+ =+0.77 V
       1/2 I2(s) / I− =+ 0.54V, Ag+ /Ag = + 0.88 V
Based on the above potentials strongest oxidising agent will be 
(a) Cu
(b) Fe3+
(c) Ag+
(d) I2           

Answer

C

Question. In the cell reaction,
Cu(s) + 2Ag+ (aq)→ Cu2+ (aq) + 2Ag(s),E°cell  = 0.46 V by doubling the concentration of Cu2+ , Ecell is
(a) doubled
(b) halved
(c) increased but less than double
(d) decreased by a small fraction               

Answer

D

Question. For a saturated solution of AgCl at 25°C, specific conductance is 3.41 ×10−6 omh–1 cm–1 and that water used for preparing the solution was
1.60×10−6 ohm–1 cm–1 The solubility product of AgCl is [LeqAgCl) =138.3 ohm–1 cm–1 equiv–1]
(a) 1.31 × 10−5
(b) 1.74 × 10−8
(c) 1.72 × 10−10
(d) 3.61 × 10−3             

Answer

C

Question. The ionic conductance of Ba2+ and Cl are respectively 127 and 76 Ω cm2 as infinite dilution. The equivalent conductance (in Ω-1 cm2) of BaCl2 at infinite dilution will be 
(a) 330
(b) 203
(c) 139.5
(d) 51     

Answer

C

Question. AgNO3 (aq) was added to an aqueous KC! solution gradually and the conductivity of the solution was measured. The plot of conductance (A) versus the volume of AgNO3 is

MCQ Questions Chapter 3 Electrochemistry Class 12 Chemistry

(a) (I)
(b) (II)
(c) (III)
(d) (IV)     

Answer

D

Question. Resistance of 0.2 M solution of an electrolyte is 50 Ω. The specific conductance of the solution is 1.3 sm-1 . If resistance of the 0.4 M solution of the same electrolyte is 260 Ω, its molar conductivity is 
(a) 6250 Sm2 mol-1
(b) 6.25 x 10-4 Sm2 mol-1
(c) 625 x 10-4 Sm2 mol-1
(d) 62.5 Sm2 mol-1       

Answer

B

Question. The resistance of IN solution of acetic acid is 250Ω, when measured in a cell having a cell constant of 1.15 cm-1. The equivalent conduction (in ohm-1 cm2 equiv-1) of IN acetic acid is
(a) 2.3
(b) 4.6
(c) 9.2
(d) 18.4       

Answer

B

Question. The one which decreases with dilution is 
(a) molar conductance
(b) conductance
(c) specific conductance
(d) equivalent conductance       

Answer

C

Question. By diluting a weak electrolyte, specific conductivity (Kc) and equivalent conductivity (λc ) change as
(a) Both increase 
(b) Kc increases, λc  decreases
(c) Kc decreases, λc  increases
(d) Both decrease     

Answer

C

Question. Given the limiting molar conductivity as
∧0m(HCI) = 425. 9 Ω-1 cm2 mol-1
∧0m(NaCl)= 126.4 Ω-1 cm2 mol-1
∧0m(CH3COONa) = 91 Ω-1 cm2 mol-1
The molar conductivity, at infinite dilution, of acetic acid (in Ω-1 cm2 mol-1) will be 
(a) 481.5
(b) 390.5
(c) 299.5
(d) 516.9     

Answer

B

Question. The molar conductivities of KCl, NaCl and KNO3 are 152, 128 and 111 S cm2 mol-1 respectively. What is the molar conductivity of NaNO3
(a) 101 cm2 mol-1
(b) 87 cm2 mol-1
(c) – 101 cm2 mol-1
(d) – 391 cm2 mol-1       

Answer

B

Question. Which one of the following solutions will have highest conductivity? 
(a) 0.1 M CH3COOH
(b) 0.1 M NaCl
(c) 0.1 M KNO3
(d) 0.1 M HCl     

Answer

D

Question. Which of the following electrolytic solutions has the least specific conductance?
(a) 0.02 N
(b) 0.2 N
(c) 2 N
(d) 0.002 N     

Answer

D

Question. The resistance of N/10 solution is found to be 2.5 x 103 Ω. The equivalent conductance of the solution is ( cell constant = 1.25 cm-1 ) 
(a) 2.5 Ω-1 cm2 equiv-1
(b) 5. Ω-1 cm2 equiv-1
(c) 2.5 Ω-1 cm-2 equiv-1
(d) 5.0 Ω-1 cm-2 equiv-1     

Answer

B

Question. The value of Aeq for NH4Cl, NaOH and NaCl are respectively, 149.74, 248.1 and 126.4 Ω-1 cm-2 equiv-1 . The value of Aeqof NH4OH is
(a) 371.44
(b) 271.44
(c) 71.44
(d) Cannot be predicted from given data     

Answer

B

Question. Which of the following is not true?
(a) Cathode is negative terminal in an electrolytic cell
(b) Anode is positive terminal in a galvanic cell
(c) Reduction occurs at cathode in either of cells
(d) Oxidation occurs at anode                 

Answer

B

Question. Which of the following statement is correct?
(a) Ecell and ΔrG of cell reaction both are extensive properties
(b) Ecell and ΔrG of cell reaction both are intensive properties
(c) Ecell is an intensive property while ΔrGof cell reaction is an extensive property
(d) Ecell is an extensive property while ΔrG of cell reaction is an intensive property         

Answer

C

Question. The standard emf of a cell, involving one electron change is found to be 0.591V at 25°C. The equilibrium constant of the reaction is(1F = 96500 Cmol–1)
(a) 1.0 × 101
(b) 1.0 × 105
(c) 1.0 × 1010
(d) 1.0 × 1030           

Answer

C

Question. A gas X at 1 atm is bubbled through a solution containing a mixture of 1 MY and 1 MZ at 25°C. If the order of reduction potentials is Z > Y > X, then
(a) Y will oxidise X and not Z
(b) Y will oxidise Z and not X
(c) Y will oxidise both X and Y
(d) Y will reduce both X and Y               

Answer

A

Question. Given, E °Fe3+ /Fe = − 0.036 V, E °Fe2+ /Fe = −0.439 V
The value of standard electrode potential for the charge,
Fe3+(aq) + e− →Fe2+ (aq) will be
(a) – 0.072 V
(b) 0.385 V
(c) 0.770 V
(d) – 0.270 V                 

Answer

C

Question. Given below are the half-cell reactions
       Mn2+ + 2e → Mn ;E° 1.18eV 
      2(Mn3+ +e → Mn2+ ); E ° = + 1.51 eV 
      The  ° for 3Mn2+ → Mn + 2Mn3+ will be
(a) −2.69V; the reaction will not occur
(b) −2.69V; the reaction will occur
(c) −0.33 V; the reaction will not occur
(d) −0.33 V; the reaction will occur             

Answer

A

Question. Of the following metals that cannot be obtained by electrolysis of the aqueous solution of their salts are
(a) Ag and Mg
(b) Ag and Al
(c) Mg and Al
(d) Cu and Cr           

Answer

C

Question. The standard reduction potentials for Zn2+ / Zn, Ni2+ / Ni  and Fe2+ /Fe are − 0.76, − 0.23 and − 0.44 V respectively. The reaction X + Y 2+ → X 2+ + Y will be spontaneous when
(a) X = Ni,Y = Fe
(b) X = Ni,Y = Zn
(c) X = Fe,Y = Zn
(d) X = Zn,Y = Ni           

Answer

B

Question. Same quantity of charge is being used to liberate iodine (at anode) and a metalM (at cathode). The mass of metalM liberated is 0.617 g and the liberated iodine is completely reduced by 46.3 mL of 0.124 M sodium thiosulphate. What is the total time to bring this change if 10 A current is passed through solution of metal iodide?
(a) 55.4 s
(b) 25.2 s
(c) 5.54 s
(d) 16.8 s                 

Answer

A

Question. Galvanisation is applying a coating of 
(a) Cr
(b) Cu
(c) Zn  
(d) Pb             

Answer

C

Question. Aluminium oxide may be electrolysed at 1000°C to furnish aluminium metal
(Atomic mass = 27u; 1F = 96500 C).
The cathode reaction is Al3+ + 3e → Al.
To prepare 5.12 kg of aluminium metal by this method required electricity will be
(a) 5.49 × 101C
(b) 5.49 ×  104C
(c) 1.83 × 107C
(d) 5.49 × 107C               

Answer

D

Question. How long (approximate) should water be electrolysed by passing through 100 A current so that the oxygen released can completely burn 27.66 g of diborane? (Atomic weight of B =10 8 . μ) 
(a) 6.4 h
(b) 0.8 h
(c) 3.2 h
(d) 1.6 h             

Answer

C

Question. Given the data at 25°C,
                        Ag + I → AgI +e; E ° = 0.152 V
                       Ag Ag+ → + e; E ° = − 0.800 V
What is the value of log Ksp for AgI ?
{2.303 RT/F = 0.059 V}
(a) − 8.12
(b) + 8.612
(c) −37.83
(d) −16.14             

Answer

D

Question. The Edison storage cell is represented as
    Fe(s)|FeO(s)|KOH(aq)| Ni2O3(s)|NiO(s)|Ni (s)
the half-cell reactions are
Ni2O3(s)+H2O(l )+ 2e ⇌ 2NiO(s)+ 2OH
FeO(s)+H2O(l )+2e ⇌ e(s)+ 2OH−; eF E ° =− 0.87V
What is the maximum amount of electrical energy that can be obtained from one mole of Ni2O3?
(a) 127 kJ
(b) 245.11 kJ
(c) 90.71 kJ
(d) 122.55 kJ               

Answer

B

Question. The standard oxidation potentials of Zn, Cu, Ag and Ni electrodes are + 0.76, – 0. 34, – 0. 80 and + 0. 25 V respectively. Which of the following reaction will provide maximun1 voltage?
(a) Cu + 2Ag+ (aq) ➔ Cu2+ (aq) + 2Ag
(b) Zn + 2Ag+ (aq) ➔ Zn2+ (aq) + 2Ag
(c) H2 + Ni2+ (aq) ➔ 2H+ (aq) + Ni
(d) Zn + Cu2+ (aq) ➔ Zn2+ (aq) + Cu
(e) Zn + 2H+ (aq) ➔ Zn2+ (aq) + H2

Answer

B

Question. The standard emf of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 25C° . The equilibrium constant of the reaction would be
(Given, F = 96500Cmol-1, R = 8.3 14 JK-1 mol-1)
(a) 2.0 X 1011
(b) 4.0 X 1012 
(c) 1.0 x 102
(d) 1.0 x 1010

Answer

D

Question. The cell reaction of a cell is
Mg(s) + Cu2+ (aq) ➔ Cu (s) + Mg2+ (aq). If the standard reduction potentials of Mg and Cu are – 2. 37 and + 0. 34 V respectively. The emf of the cell is 
(a) 2.03 V
(b) – 2.03 V
(c) + 2.71 V
(d) – 2.71 V

Answer

C

Question. EMF of hydrogen electrode in te1m of pH is ( at 1 atrn pressure) 
(a) EH2 = RT/F x pH
(b) EH2 =RT/F.1/pH
(c) EH2 = 2.303 RT/F.pH
(d) EH2 = 0.0591 pH

Answer

D

Question. For the redox reaction,
Zn(s) + Cu2+ (0.1 M) ➔ Znz+ (1 M) + Cu(s)
taking place in a cell, E°cell is 1.10 V. E°cell for the cell willbe ( 2.303 RT/F = 0.0591) 
(a) 2.14 V
(b) 1.80 V
(c) 1.07 V
(d) 0.82 V

Answer

C

Question. Sn4+ + 2e ➔ Sn2+, E° = 0. 13 V
Br2 + 2e ➔ 2Br ,E° = 1 .08V
Calculate K eq for the cell reaction for the cell formed by two electrodes. 
(a) 1041
(b) 1032
(c) 10-32
(d) 10-42

Answer

B

Question. Calculate the emf of the cell
Cu(s) l Cuz+ (aq) ll Ag+ (aq ) l Ag(s)
Given, E°Cu2+/Cu = + 0.34 V, E°Ag+ /Ag = 0.80 V
(a) + 0.46 V
(b) + 1.14 V 
(c) +0.57 V
(d) -0.46 V   

Answer

A

Question. The standard electrode potential of hydrogen electrode at 1 M concentration and hydrogen gas at 1 atrn pressure is
(a) 1 V
(b) 6 V 
(c) 8 V
(d) 0 V   

Answer

D

Question. 2Fe3+ + 3I ⇌ 2Fe2+ + I3
The standard reduction potentials in acidic conditions are 0.77 and 0.54V respectively for Fe3+ / Fe2+ and I3/ I rcouples. The equilibrium constant for the reaction is
(a) 6.26 X 10-7
(b) 5.33 X 10-4
(c) 6.26 x 107
(d) 5.33 x 104   

Answer

C

Question. Which one of the following nitrates will leave behind a metal on strong heating?
(a) Ferric nitrate
(b) Copper nitrate
(c) Manganese nitrate
(d) Silver nitrate   

Answer

D

Question. An alloy of Pb-Ag weighing 1.08 g was dissolved in dilute HNO3 and the volume made to 100 mL. A silver electrode was dipped in the solution and the emf of the cell set-up Pt(s ), H2 (g) l H+ (l M) ll Ag+ (aq) l Ag(s) was 0.62 V. If E°cell = 0. 80V, what is the percentage of Ag in the alloy? (At 25°C, RT/F = 0. 06) 
(a) 25
(b) 2.50
(c) 10
(d) 1
(e) 50

Answer

E

Question. In the electrochemical reaction,
2Fe3+ + Zn ➔ Zn2+ + 2Fe2+
increasing the concentration of Fe2+ 
(a) increases cell emf
(b) increases the current flow
(c) decreases the cell emf
(d) alter the pH of the solution

Answer

C

Question. Given the data at 25°C,
Ag + I ➔ AgI + e ;E° =0. 152 V
Ag ➔ Ag+ + e- ; E° = – 0. 800 V
What is the value of log Ksp for AgI?
( 2.303RT/F = 0.059 V)
(a) – 8.12
(b) +8.612
(c) – 37.83
(d) -16.13

Answer

D

Question. An inaccurate ammeter and silver coulometer is connected in series in an electric circuit through which a constant direct current flows. If ammeter reads 0.6 ampere throughout one hour, the silver deposited on coulometer was found to be 2.16 g. What per cent error is in the reading of ammeter ? [Assume 100% current efficiency].
(a) 1%
(b) 0.54%
(c) 0.06 %  
(d) 10%                     

Answer

D

Question.  An aqueous solution ofNaCl on electrolysis gives H2(g),Cl2(g) and NaOH. According to reaction,
 2Cl(aq)+ 2H2O → 2OH− (aq)+H2(g) + Cl2(g)
A direct current of 25 A with a current efficiency of 62% is passed through 20 L of NaCl solution (20% by weight). How long it take to produce 1 kg of Cl2?
(a) 30.20 h
(b) 12.17 h
(c) 48.71 h
(d) 14.61 h               

Answer

C

Question.  Zn|Zn2+ (a = 0.1 M)||Fe2+ (a = 0.01 M)|Fe.
The emf of the above cell is 0.2905 V.
Equilibrium constant for the cell reaction is
(a) 10 0.32/ 0.0591
(b) 10 0.32/ 0.0295
(c) 10 0.26/ 0.0295
(d) 10 0.32/ 0.295             

Answer

B

Question. The standard reduction potentials at 298 K for the following half reactions are given against each.
         Zn2+ (aq) + 2e ⇌ Zn(s); – 0.762 V
         Cr3+ (aq) + 3e ⇌ Cr(s); – 0.740 V
        2H+ (aq  + 2e– ⇌ H2(g); 0.00 V
        Fe3+ (aq) + e ⇌ Fe2+  2+ (aq); 0.770
Which is the strongest reducing agent?
(a) Zn (s)
(b) Cs (s)
(c) H2 (g)
(d) Fe3+ (aq)                 

Answer

A

Question. The equivalent conductances of two strong electrolytes at infinite dilution inH O 2 (where ions move freely through a solution) at 25°C are given below
Λ° = CH3COONa = 91.0 S cm2 /equiv
Λ° HCl = l 2 426.2 S cm2 /equiv
What additional information/quantity one needs to calculate Λ° of an aqueous solution of acetic acid ?
(a) Λ° of NaCl
(b) Λ° of CH3COK 
(c) The limiting equivalent conductance of H+ [λ° H+ ]
(d) Λ° of chloroacetic acid (ClCH2COOH)             

Answer

A

Question.  The rusting of iron takes place as follows:
      2H+ 2e + 1/2 O2  → H2O (l);E °=+1.23 V
            Fe2+ + 2e → Fe (s) ;E °= – 0.44 V
Calculate ΔG° for the net process.
(a) –322 kJmol–1
(b) –161 kJmol–1
(c) –152 kJmol–1
(d) –76 kJmol–1               

Answer

A

Question. The cell, Zn| Zn (1M) | | Cu (1M)| Cu 2+ 2+
(E °cell = 1.10 V), was allowed to be completely discharged at 298 K. The relative concentration of Zn2+ to Cu2+ {[Zn2+ / Cu2+] 2+   [Zn ] [Cu ] is
(a) antilog (24.08)
(b) 37.2
(c) 1037.2
(d) 9.65 × 104               

Answer

C

MCQ Questions Chapter 3 Electrochemistry Class 12 Chemistry

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